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dc.contributor.authorEs Sih, Salima
dc.contributor.authorFranco-Duro, Francisco Ignacio 
dc.contributor.authorGarcía-Sancho, Cristina 
dc.contributor.authorGarcía-Mateos, Francisco José 
dc.contributor.authorRosas-Martínez, Juana María 
dc.contributor.authorMoreno-Tost, Ramón 
dc.contributor.authorMaireles-Torres, Pedro Jesús 
dc.contributor.authorCecilia-Buenestado, Juan Antonio 
dc.date.accessioned2024-05-29T09:33:01Z
dc.date.available2024-05-29T09:33:01Z
dc.date.issued2024
dc.identifier.citationEs Sih, S., Franco-Duro, F., García-Sancho, C. et al. Valorization of Furfural to Obtain High Value-Added Products with ZrO2- and Al2O3-Pillared Clays. Top Catal (2024). https://doi.org/10.1007/s11244-024-01971-3es_ES
dc.identifier.urihttps://hdl.handle.net/10630/31429
dc.description.abstractTwo phyllosilicates (montmorillonite and saponite) have been selected as starting materials to synthesize ZrO2- and Al2O3-pillared clays by the insertion of polyoxocations and subsequent calcination. These pillared clays display higher surface area, porosity and available acid sites in comparison to their respective raw clays. These samples were tested in the one-pot process to transform furfural into obtain valuable products. The incorporation of ZrO2 allows to reach the highest furfural conversion values, with high yields towards furfuryl alcohol (FOL) at shorter reaction times, whereas the formation of i-propyl furfuryl ether (iPFE) is favored at longer times, attaining iPFE yields of about 50% after 24 h at 170 ºC, using isopropanol as sacrificing alcohol.es_ES
dc.description.sponsorshipFunding for open access charge: Universidad de Málaga / CBUAes_ES
dc.language.isoenges_ES
dc.publisherSpringeres_ES
dc.rightsinfo:eu-repo/semantics/openAccesses_ES
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/*
dc.subjectAldehídos - Reactividades_ES
dc.subjectFilosilicatos - Reactividades_ES
dc.subject.otherPillared clayses_ES
dc.subject.otherFurfurales_ES
dc.subject.otherOne-pot reactiones_ES
dc.subject.otherFurfuryl alcoholes_ES
dc.subject.otherAlkyl furfuryl etheres_ES
dc.subject.otherAlkyl levulinatees_ES
dc.subject.otherγ-valerolactonees_ES
dc.titleValorization of furfural to obtain high value-sdded products with ZrO2- and Al2O3-Pillared clayses_ES
dc.typeinfo:eu-repo/semantics/articlees_ES
dc.identifier.doihttps://doi.org/10.1007/s11244-024-01971-3
dc.rights.ccAttribution-NonCommercial-NoDerivatives 4.0 Internacional*
dc.type.hasVersioninfo:eu-repo/semantics/publishedVersiones_ES


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