Mostrar el registro sencillo del ítem

dc.contributor.authorMaderuelo-Solera, Rocío
dc.contributor.authorLópez Asencio, Raquel
dc.contributor.authorCecilia-Buenestado, Juan Antonio 
dc.contributor.authorJiménez-Gómez, Carmen Pilar
dc.contributor.authorGarcía-Sancho, Cristina 
dc.contributor.authorMoreno-Tost, Ramón 
dc.contributor.authorMaireles-Torres, Pedro Jesús 
dc.date.accessioned2022-09-16T12:10:54Z
dc.date.available2022-09-16T12:10:54Z
dc.date.issued2019-11-07
dc.identifier.urihttps://hdl.handle.net/10630/25020
dc.description.abstractCatalytic transfer hydrogenation is an alternative catalytic approach for the reduction of carbonyl groups, instead of the use of dihydrogen gas. In this sense, a series of catalysts has been prepared by thermal treatment of layered double hydroxides, hydrotalcite type, of Mg(II) and Fe(III), with different Mg/Fe molar ratios. The resulting mixture of metal oxides was characterized by X-ray diffraction, TEM, N2 adsorption-desorption, CO2-TPD, NH3-TPD and XPS, and then catalysts were tested in the Meenwein-Ponndorf-Verley (MPV) reduction of furfural to obtain furfuryl alcohol. The catalytic results show that the catalysts with a Mg/Fe molar ratio of 3 allows reaching the highest furfural conversion at a lower reaction time, with a FOL yield close to 90% after 6 h of reaction at 443 K. The detailed analysis of these catalysts also revealed that the basicity has a more predominant role in the MPV reaction than acid sites.es_ES
dc.description.sponsorshipSpanish Ministry of Innovation, Science and Universities (Project RTI2018-094918-B-C44) and FEDER (European Union) funds. J.A.C. and C.G.S. thank University of Malaga for contracts of PhD incorporation. R.M.T. thanks to the Spanish Ministry of Economy and Competitiveness (IEDI-2016-00743) for the financial support within the I3 program.es_ES
dc.language.isoenges_ES
dc.publisherElsevier B.V.es_ES
dc.rightsinfo:eu-repo/semantics/openAccesses_ES
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/*
dc.subjectCatálisises_ES
dc.subjectHidrogenaciónes_ES
dc.subject.otherMg/Fe hydrotalciteses_ES
dc.subject.otherHeterogeneous catalystses_ES
dc.subject.otherFurfurales_ES
dc.subject.otherFurfuryl alcoholes_ES
dc.subject.otherCatalytic transfer hydrogenationes_ES
dc.titleCatalytic transfer hydrogenation of furfural to furfuryl alcohol over calcined MgFe hydrotalciteses_ES
dc.typeinfo:eu-repo/semantics/articlees_ES
dc.centroFacultad de Cienciases_ES
dc.identifier.doi10.1016/j.clay.2019.105351
dc.rights.ccAttribution-NonCommercial-NoDerivatives 4.0 Internacional*
dc.type.hasVersioninfo:eu-repo/semantics/submittedVersiones_ES


Ficheros en el ítem

Este ítem aparece en la(s) siguiente(s) colección(ones)

Mostrar el registro sencillo del ítem

Attribution-NonCommercial-NoDerivatives 4.0 Internacional
Excepto si se señala otra cosa, la licencia del ítem se describe como Attribution-NonCommercial-NoDerivatives 4.0 Internacional