ListarQICM - Artículos por tema "Química inorgánica"
Mostrando ítems 1-17 de 17
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“Breathing” in Adsorbate-Responsive Metal Tetraphosphonate Hybrid Materials
(Wiley-VCH Verlag GmbH&Co. KGaA, Weinheim, 2009-05-28)The structures of various layered calcium tetraphosphonates (CaH6DTMP; H8DTMP=hexamethyl- tetrakis(methylenephosphonic acid)), have been determined. Starting from CaH6DTMP·2H2O, thermal treatment and subsequent exposure ... -
Common Structural Features in Calcium Hydroxyphosphonoacetates. A High-Throughput Screening
(2011-03-11)R,S-Hydroxyphosphonoacetic acid (H3HPA) is an inexpensive multidentate organic ligand widely used for the preparation of organo-inorganic hybrid materials. There are reports of several crystal structures and the variability ... -
Divalent Metal Vinylphosphonate Layered Materials: Compositional Variability, Structural Peculiarities, Dehydration Behavior, and Photoluminescent Properties
(American Chemical Society, 2011-09-27)A family of M-VP (M = Ni, Co, Cd, Mn, Zn, Fe, Cu, Pb; VP = vinylphosphonate) and M-PVP (M = Co, Cd; PVP = phenylvinylphosphonate) materials have been synthesized by hydrothermal methods and characterized by FTIR, elemental ... -
High Proton Conductivity in a Flexible, Cross-Linked, Ultramicroporous Magnesium Tetraphosphonate Hybrid Framework
(American Chemical Society, 2012-07-03)Multifunctional materials, especially those combining two or more properties of interest, are attracting immense attention due to their potential applications. MOFs, metal organic frameworks, can be regarded as multifunctional ... -
Insights into the Dynamics of Grotthuss Mechanism in a Proton- Conducting Chiral bioMOF
(American Chemical Society, 2016-06-13)Proton conduction in solids attracts great interest, not only because of possible applications in fuel cell technologies, but also because of the main role of this process in many biological mechanisms. Metal−organic frameworks ... -
Multifunctional lanthanum tetraphosphonates: Flexible, ultramicroporous and proton-conducting hybrid frameworks
(The Royal Society of Chemistry, 2012)A new flexible ultramicroporous solid, La(H5DTMP)·7H2O (1), has been crystallized at room temperature using the tetraphosphonic acid H8DTMP, hexamethylenediamine-N,N,N′,N′-tetrakis(methylenephosphonic acid). Its crystal ... -
Phase Transformation Dynamics in Sulfate-Loaded Lanthanide Triphosphonates. Proton Conductivity and Application as Fillers in PEMFCs
(ACS Publications. American Chemical Society, 2021)Phase transformation dynamics and proton conduction properties are reported for cationic layer-featured coordination polymers derived from the combination of lanthanide ions (Ln3+) with nitrilo-tris(methylenephosphonic ... -
Portland and belite cement hydration acceleration by C-S-H seeds with variable w/c ratios
(Materials, 2022)The acceleration of very early age cement hydration by C-S-H seeding is getting attention from scholars and field applications because the enhanced early age features do not compromise later age performances. This acceleration ... -
Recent Advances in C-S-H Nucleation Seeding for Improving Cement Performances
(MDPI, 2023)Reducing cement CO2 footprint is a societal need. This is being achieved mainly by replacing an increasing amount of Portland clinker by supplementary cementitious materials. However, this comes at a price: lower mechanical ... -
Selective Catalytic Reduction of NOx by CO over Cu(Fe)/SBA-15 Catalysts: Effects of the Metal Loading on the Catalytic Activity
(IOAP-MDPI, 2023-03-04)Mesoporous Cu(Fe)/SBA-15 catalysts were prepared with distinct metal loadings of ca. 2–10 wt.%. A detailed set of characterizations using X-ray diffraction (XRD), electron paramagnetic resonance (EPR), transmission electron ... -
Structural Landscape and Proton Conduction of Lanthanide 5-(Dihydroxyphosphoryl)isophthalates
(ACS Publications, 2024)Metal phosphonate-carboxylate compounds repre-sent a promising class of materials for proton conductionapplications. This study investigates the structural, thermal, andproton conduction properties of three groups of ... -
Structural Mapping and Framework Interconversions in 1D, 2D, and 3D Divalent Metal R,S-Hydroxyphosphonoacetate Hybrids
(American Chemical Society, 2009-12-16)Reactions of divalent cations (Mg2þ, Co2þ, Ni2þ, and Zn2þ) with R,S-hydroxyphosphonoacetic acid (HPAA) in aqueous solutions (pH values ranging 1.0-4.0) yielded a range of crystalline hydrated M-HPAA hybrids. Onedimensional ... -
Structural Variability in Multifunctional Metal Xylenediaminetetraphosphonate Hybrids
(American Chemical Society, 2013-07-24)Two new families of divalent metal hybrid derivatives from the aromatic tetraphosphonic acids 1,4- and 1,3-bis(aminomethyl)benzene-N,N′-bis(methylenephosphonic acid), (H2O3PCH2)2−N−CH2C6H4CH2−N(CH2PO3H2)2 (designated herein ... -
Synthesis and structural characterization of 2-D layered copper(II) styrylphosphonate coordination polymers
(Taylor & Francis, 2014-04-11)We report the synthesis, physicochemical characterization, and crystal structure of Cu-SP (SP = styrylphosphonic acid, H2O3PCH=CH2(C6H5)), the first reported example of a metal derivative of SP. The starting SP acid was ... -
Synthesis and structural characterization of homochiral 2D coordination polymers of zinc and copper with conformationally flexible ditopic imidazolium-based dicarboxylate ligands
(The Royal Society of Chemistry, 2016-11-30)Different novel coordination polymers containing zinc, 1–4, and copper, 5–8, metals, connected via chiral imidazolium-based dicarboxylate ligands, [LR]−, were isolated by reaction between zinc acetate or copper acetate ... -
Tuning Proton Conductivity in Alkali Metal Phosphonocarboxylates by Cation Size-Induced and Water-Facilitated Proton Transfer Pathways
(American Chemical Society, 2014-12-20)The structural and functional chemistry of a family of alkali-metal ions with racemic R,S-hydroxyphosphonoacetate (M-HPAA; M = Li, Na, K, Cs) are reported. Crystal structures were determined by X-ray data (Li+, powder ... -
X-ray near-field ptychographic nanoimaging of cement pastes
(Elsevier, 2024)The hydration processes of Portland cements (PC) and blends are complicated as there are many components with great heterogeneity at different length scales. Thus, 3D nanoimaging techniques with high spatial resolution and ...