Listar QICM - Artículos por autor "Bazaga-García, Montse"
Mostrando ítems 1-20 de 21
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Exploiting the Multifunctionality of M2+/Imidazole−Etidronates for Proton Conductivity (Zn2+) and Electrocatalysis (Co2+, Ni2+) toward the HER, OER, and ORR
Vílchez-Cózar, Álvaro; Armakola, Eirini; Gjika, Maria; Visa, Aurelia; Bazaga-García, Montse; Olivera-Pastor, Pascual
; Choquesillo-Lazarte, Duane; Marrero-López, David; Cabeza-Díaz, Aurelio; Pérez-Colodrero, Rosario Mercedes; Demadis, Konstantinos D.[et al.] (American Chemical Society, 2022-02-22)
This work deals with the synthesis and characterization of one-dimensional (1D) imidazole-containing etidronates, [M2(ETID)(Im)3]·nH2O (M = Co2+ and Ni2+; n = 0, 1, 3) and Zn2(ETID)2(H2O)2](Im)2, as well as the corresponding ... -
From light to heavy alkali metal tetraphosphonates (M = Li, Na, K, Rb, Cs): cation size-induced structural diversity and waterfacilitated proton conductivity
Salcedo, Inés R.; Pérez-Colodrero, Rosario Mercedes; Bazaga-García, Montse; Vasileiou, Antonia; Papadaki, Maria; Olivera-Pastor, Pascual; Infantes-Molina, Antonia; Ramírez-Losilla, Enrique; Mezei, Gellert; Cabeza-Díaz, Aurelio; Demadis, Konstantinos D.[et al.] (The Royal Society of Chemistry, 2018-09)
A family of alkali metal-based frameworks containing the tetraphosphonate ligand hexamethylenediamine- N,N,N′,N′-tetrakisIJmethylenephosphonic acid), HDTMP, is reported. A cation size-induced structural diversity, from ... -
Guest Molecule-Responsive Functional Calcium Phosphonate Frameworks for Tuned Proton Conductivity
Bazaga-García, Montse; Pérez-Colodrero, Rosario Mercedes; Papadaki, M.; Garczarek, Piotr; Zon, Jerzy; Olivera-Pastor, Pascual; Losilla, Enrique R.; León-Reina, Laura; García-Aranda, Miguel Ángel; Choquesillo-Lazarte, Duane; Demadis, Konstantinos D.; Cabeza-Díaz, Aurelio[et al.] (American Chemical Society, 2014-03-18)
We report the synthesis, structural characterization, and functionality of an open-framework hybrid that combines Ca2+ ions and the rigid polyfunctional ligand 5-(dihydroxyphosphoryl) isophthalic acid (PiPhtA). Ca-PiPhtA-I ... -
High-Throughput Synthesis of Pillared-Layered Magnesium Tetraphosphonate Coordination Polymers: Framework Interconversions and Proton Conductivity Studies
Pérez-Colodrero, Rosario Mercedes; Salcedo, Inés R.; Bazaga-García, Montse; Barouda, Eleni; Papadaki, Maria; Papathanasiou, Konstantinos E.; Hernández Alonso, Daniel; Rius, Jordi; García-Aranda, Miguel Ángel; Ramírez-Losilla, Enrique; Olivera-Pastor, Pascual; Demadis, Konstantinos D.; Cabeza-Díaz, Aurelio[et al.] (MDPI, www.mdpi.com/journal/inorganics, 2018-09-11)
Novel pillared-layered framework materials were synthesized by high-throughput or microwave-assisted methodology that contain Mg2+ and the zwitterionic linker HDTMP (hexamethylenediamine-N,N,N0,N0-tetrakis(methylenephosphonic ... -
Influence of Proton Conducting Cations on the Structure and Properties of 2D Anilate-Based Magnets
Palacios Corella, Mario; Fernández Espejo, Alejandro; Bazaga-García, Montse; Ramírez-Losilla, Enrique; Cabeza-Díaz, Aurelio; Clemente-León, Miguel; Coronado, Eugenio[et al.] (ACS publications, 2017-11-01)
The syntheses, structures, magnetic, and proton conductivity properties of a family of bimetallic anilate-based compounds with inserted alkylammonium cations are presented. The structures of (Me2NH2)[MnIICrIII(Br2An)3]·2H2O ... -
Insights into the Dynamics of Grotthuss Mechanism in a Proton- Conducting Chiral bioMOF
Grancha, Thais; Ferrando-Soria, Jesús; Cano, Joan; Amorós, Pedro; Seoane, Beatriz; Gascón, Jorge; Bazaga-García, Montse; Losilla, Enrique R.; Cabeza-Díaz, Aurelio; Armentano, Donatella; Pardo, Emilio[et al.] (American Chemical Society, 2016-06-13)
Proton conduction in solids attracts great interest, not only because of possible applications in fuel cell technologies, but also because of the main role of this process in many biological mechanisms. Metal−organic frameworks ... -
Layered Lanthanide Sulfophosphonates and Their Proton Conduction Properties in Membrane Electrode Assemblies
Bazaga-García, Montse; Salcedo, Inés R.; Pérez-Colodrero, Rosario Mercedes; Xanthopoulos, Konstantinos; Villemin, Didier; Stock, Norbert; López-González, Mar; Del Río, Carmen; Ramírez-Losilla, Enrique; Cabeza-Díaz, Aurelio; Demadis, Konstantinos D.; Olivera-Pastor, Pascual[et al.] (ACS publications, 2019-11-07)
Metal phosphonates containing acidic groups exhibit a wide range of proton conduction properties, which may enhance the performance of membrane electrode assemblies (MEAs). In this work, focus is placed on proton conduction ... -
Luminescent and Proton Conducting Lanthanide Coordination Networks Based On a Zwitterionic Tripodal Triphosphonate
Bazaga-García, Montse; Angeli, Giasemi K.; Papathanasiou, Konstantinos E.; Salcedo, Inés R.; Olivera-Pastor, Pascual; Losilla, Enrique R.; Choquesillo-Lazarte, Duane; Hix, Gary B.; Cabeza-Díaz, Aurelio; Demadis, Konstantinos D.[et al.] (American Chemical Society, 2016-07-14)
The synthesis, structural characterization, luminescence properties, and proton conduction performance of a new family of isostructural cationic 2D layered compounds are reported. These have the general formula ... -
NH3/H2O-mediated proton conductivity and photocatalytic behaviour of Fe(II)-hydroxyphosphonoacetate and M(II)-substituted derivatives
Salcedo, Inés R.; Bazaga-García, Montse; Cuesta-García, Ana María; Ramírez-Losilla, Enrique; Demadis, Konstantinos D.; Olivera-Pastor, Pascual; Pérez-Colodrero, Rosario Mercedes; Cabeza-Díaz, Aurelio[et al.] (The Royal Society of Chemistry, 2019-12-27)
Synthesis redesign and derivatisation of Fe(II)-hydroxyphosphonoacetate, incorporating different ammonia loads and M(II) isomorphic substitutions (M = Mn, Co and Zn), have been implemented. The NH3 adsorption led to materials ... -
Phase Transformation Dynamics in Sulfate-Loaded Lanthanide Triphosphonates. Proton Conductivity and Application as Fillers in PEMFCs
Salcedo, Inés R.; Pérez-Colodrero, Rosario Mercedes; Bazaga-García, Montse; López González, María del Mar; Del Río, Carmen; Xanthopoulos, Konstantinos; Demadis, Konstantinos D.; Hix, Gary B.; Furasova, Aleksandra D.; Choquesillo-Lazarte, Duane; Olivera-Pastor, Pascual; Cabeza-Díaz, Aurelio[et al.] (ACS Publications. American Chemical Society, 2021)
Phase transformation dynamics and proton conduction properties are reported for cationic layer-featured coordination polymers derived from the combination of lanthanide ions (Ln3+) with nitrilo-tris(methylenephosphonic ... -
Phosphonate Decomposition-Induced Polyoxomolybdate Dumbbell-Type Cluster Formation: Structural Analysis, Proton Conduction, and Catalytic Sulfoxide Reduction
Armakola, Eirini; Salcedo, Inés R.; Bazaga-García, Montse; Mezei, Gellert; Cabeza-Díaz, Aurelio; Fernandes, Tiago A.; Kirillov, Alexander M.; Demadis, Konstantinos D.[et al.] (ACS publications, 2019-08-12)
The reaction of MoO4^2− with a number of phosphonic acids [bis-(phosphonomethyl)glycine, R,S-hydroxyphosphonoacetic acid, 1-hydroxyethane-1,1-diphosphonic acid, phenylphosphonic acid, aminotris(methylene phosphonic acid), ... -
Photodegradation of Phenol over a Hybrid Organo-Inorganic Material: Iron(II) Hydroxyphosphonoacetate
Bazaga-García, Montse; Cabeza-Díaz, Aurelio; Olivera-Pastor, Pascual; Santacruz-Cruz, María Isabel; Pérez-Colodrero, Rosario Mercedes; García-Aranda, Miguel Ángel[et al.] (American Chemical Society, 2012-06-20)
Water treatment is a hot topic, and it will become much more important in the decades ahead. Advanced oxidation processes are being increasingly used for organic contaminant removal, for example using photo-Fenton reactions. ... -
Properties and Applications of Metal Phosphates and Pyrophosphates as Proton Conductors
Pérez-Colodrero, Rosario Mercedes; Olivera-Pastor, Pascual; Cabeza-Díaz, Aurelio; Bazaga-García, Montse (MDPI, 2022-02-09)
We review the progress in metal phosphate structural chemistry focused on proton conductivity properties and applications. Attention is paid to structure–property relationships, which ultimately determine the potential ... -
Structural and Proton Conductivity Studies of Fibrous π-Ti2O(PO4)2·2H2O: Application in Chitosan- Based Composite Membranes
Babaryk, Artem A.; Adawy, Alaa; García, Inés; Trobajo, Camino; Amghouz, Zakariae; Pérez-Colodrero, Rosario Mercedes; Cabeza-Díaz, Aurelio; Olivera-Pastor, Pascual; Bazaga-García, Montse; Dos-Santos-Gómez, Lucía[et al.] (The Royal Society of Chemistry, 2021)
Although the fibrous polymorphic modification of titanium phosphate, π-Ti2O(PO4)2·2H2O (π-TiP) is known for decades, its crystal structure has remained unsolved. Herewith we report the crystal structure of π-TiP at a room ... -
Structural Landscape and Proton Conduction of Lanthanide 5-(Dihydroxyphosphoryl)isophthalates
Salcedo, Inés R.; Bazaga-García, Montse; Pérez-Colodrero, Rosario Mercedes; Vílchez-Cózar, Álvaro; Cañamero-Cebrián, Fernando; Olivera-Pastor, Pascual; Zareba, Jan K.; Cabeza-Díaz, Aurelio[et al.] (ACS Publications, 2024)
Metal phosphonate-carboxylate compounds repre-sent a promising class of materials for proton conductionapplications. This study investigates the structural, thermal, andproton conduction properties of three groups of ... -
Structural variability in M2+ 2-hydroxyphosphonoacetate moderate proton conductors
Pérez-Colodrero, Rosario Mercedes; Salcedo, Inés R.; Bazaga-García, Montse; Milla-Pérez, Diego F.; Durán-Martín, Jonatan D.; Ramírez-Losilla, Enrique; Moreno-Real, Laureano; Rius, Jordi; García-Aranda, Miguel Ángel; Demadis, Konstantinos D.; Olivera-Pastor, Pascual; Cabeza-Díaz, Aurelio[et al.] (De Gruyter, 2017)
The structural variability of two series of Mg2+- and Zn2+- 2-hydroxyphosphonoacetates have been studied in the range of 25–80 °C and 95 % relative humidity in order to correlate the structure with the proton conductivity ... -
Structural Variability in Multifunctional Metal Xylenediaminetetraphosphonate Hybrids
Pérez-Colodrero, Rosario Mercedes; Angeli, Giasemi K.; Bazaga-García, Montse; Olivera-Pastor, Pascual; Villemin, Didier; Losilla, Enrique R.; Martos, Estefanía Q.; Hix, Gary B.; García-Aranda, Miguel Ángel; Demadis, Konstantinos D.; Cabeza-Díaz, Aurelio[et al.] (American Chemical Society, 2013-07-24)
Two new families of divalent metal hybrid derivatives from the aromatic tetraphosphonic acids 1,4- and 1,3-bis(aminomethyl)benzene-N,N′-bis(methylenephosphonic acid), (H2O3PCH2)2−N−CH2C6H4CH2−N(CH2PO3H2)2 (designated herein ... -
Synthesis and Electrochemical properties of metal(II)- carboxyethylphenylphosphinates
Bazaga-García, Montse; Vílchez-Cózar, Álvaro; Maranescu, Bianca; Olivera-Pastor, Pascual; Marganovici, Marko; Ilia, Gheorghe; Cabeza-Díaz, Aurelio; Visa, Aurelia; Pérez-Colodrero, Rosario Mercedes[et al.] (Royal Society of Chemistry, 2021)
We report herein the synthesis, structural characterization and electrocatalytic properties of three new coordination polymers, resulting from the combination of divalent metal (Ca2+, Cd2+ or Co2+) salts with (2-carboxy ... -
Three-Component Copper-Phosphonate-Auxiliary Ligand Systems: Proton Conductors and Efficient Catalysts in Mild Oxidative Functionalization of Cycloalkanes
Armakola, Eirini; Pérez-Colodrero, Rosario Mercedes; Bazaga-García, Montse; Salcedo, Inés R.; Choquesillo-Lazarte, Duane; Cabeza-Díaz, Aurelio; Kirillova, Marina V.; Kirillov, Alexander M.; Demadis, Konstantinos D.[et al.] (ACS publications, 2018-08-13)
The synthesis, structural characterization, topological analysis, proton conductivity, and catalytic properties are reported of two Cu(II)-based compounds, namely a dinuclear Cu(II) complex [Cu2(μ-VPA)2(phen)2(H2O)2]· 8H2O ... -
Tuning Proton Conductivity in Alkali Metal Phosphonocarboxylates by Cation Size-Induced and Water-Facilitated Proton Transfer Pathways
Bazaga-García, Montse; Papadaki, M.; Pérez-Colodrero, Rosario Mercedes; Olivera-Pastor, Pascual; Losilla, Enrique R.; Nieto-Ortega, Belén; García-Aranda, Miguel Ángel; Choquesillo-Lazarte, Duane; Cabeza-Díaz, Aurelio; Demadis, Konstantinos D.[et al.] (American Chemical Society, 2014-12-20)
The structural and functional chemistry of a family of alkali-metal ions with racemic R,S-hydroxyphosphonoacetate (M-HPAA; M = Li, Na, K, Cs) are reported. Crystal structures were determined by X-ray data (Li+, powder ...