Listar IQ - Artículos por título
Mostrando ítems 1-20 de 61
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A comparison of batch and semi-batch reactors for leaching battery cathodes (LiCoO2) under controlled addition of HCl and H2O2
Cerrillo-González, María del Mar; Villén-Guzmán, María Dolores
; Rivas-Bascon, Alvaro; Rodríguez-Maroto, José Miguel; Paz-García, Juan Manuel (Elsevier, 2024-08)
Recovery of cobalt and lithium from end-of-life Li-ion battery wastes have been evaluated in batch and semi- batch leaching systems. In this preliminary study, HCl and H2O2 were used as leaching and reducing agents, re ... -
A Kinetic Model Considering Catalyst Deactivation for Methanol-to-Dimethyl Ether on a Biomass-Derived Zr/P-Carbon Catalyst
Torres-Liñán, Javier; Ruiz-Rosas, Ramiro Rafael; Rosas-Martínez, Juana María; Rodríguez-Mirasol, José; Cordero-Alcántara, Tomás (IOAP-MDPI, 2022-01-13)
A Zr-loaded P-containing biomass-derived activated carbon (ACPZr) has been tested for methanol dehydration between 450 and 550 °C. At earlier stages, methanol conversion was complete, and the reaction product was mainly ... -
A new versatile x–y–z electrospinning equipment for nanofiber synthesis in both far and near field.
Calzado-Delgado, María del Mar; Guerrero-Pérez, María Olga; Yeung, King (Nature, 2022-03-22)
This work describes a versatile electrospinning equipment with rapid, independent, and precise x–y–z movements for large-area depositions of electrospun fibers, direct writing or assembly of fibers into sub-millimeter and ... -
Acid leaching of LiCoO2 enhanced by reducing agent. Model formulation and validation.
Cerrillo-González, María del Mar; Villén-Guzmán, María Dolores; Vereda-Alonso, Carlos; Rodríguez-Maroto, José Miguel; Paz-García, Juan Manuel (Elsevier, 2021-08-25)
In this work, a model has been formulated to describe the complex process of LiCoO2 leaching through the participation of competing reactions in acid media including the effect of H2O2 as reducing agent. The model presented ... -
Activated carbon monoliths from lignocellulosic biomass waste for electrochemical applications.
Ibeh, Paul O.; García-Mateos, Francisco José; Rosas-Martínez, Juana María; Rodríguez-Mirasol, José; Cordero-Alcántara, Tomás (Elsevier, 2019-03-05)
The valorization of lignocellulosic biomass waste into bio-based materials is proposed in this work in order to obtain low-cost materials and to reduce environmental impacts. Cylindrical activated carbon monoliths (ACMs) ... -
Activation of electrospun lignin-based carbon fibers and their performance as self-standing supercapacitor electrodes
Ruiz-Rosas, Ramiro Rafael; Cordero-Alcántara, Tomás; Rodríguez-Mirasol, José; Rosas-Martínez, Juana María; García-Mateos, Francisco José; Cazorla-Amorós, Diego; Morallón, Emilia[et al.] (2020-02-17)
The production and activation of self-standing carbon electrodes from electrospun lignin fibers was analyzed in this work. Carbon microfibers were prepared at 900 °C from air-stabilized spun cloths by direct carbonization ... -
Activation of electrospun lignin-based carbon fibers and their performance as self-standing supercapacitor electrodes
García-Mateos, Francisco José; Ruiz-Rosas, Ramiro Rafael; Rosas-Martínez, Juana María; Morallón, Emilia; Cazorla-Amorós, Diego; Rodríguez-Mirasol, José; Cordero-Alcántara, Tomás[et al.] (Elsevier, 2020)
The production and activation of self-standing carbon electrodes from electrospun lignin fibers was analyzed in this work. Carbon microfibers were prepared at 900 °C from air-stabilized spun cloths by direct carbonization ... -
Advances in electrospun composite polymer/zeolite and geopolymer nanofibers: A comprehensive review.
Schneider, Mariana; Rodríguez-Castellón, Enrique; Guerrero-Pérez, María Olga; Hotza, Dachamir; De Noni Junior, Agenor; Peralta Muniz Moreira, Regina de Fátima[et al.] (Elsevier, 2024-02-05)
Electrospinning is widely recognized as an efficient, simple, and cost-effective technique for producing nanofibers. It has successfully led to the fabrication of various ultrafine polymer composites. This method has spurred ... -
Assessment of Agricultural Residue to Produce Activated Carbon-Supported Nickel Catalysts and Hydrogen Rich Gas.
Hosseinzaei, Behnam; Hadianfard, Mohammad Jafar; Esmaeilzadeh, Feridun; Recio-Ruiz, María del Carmen; Ruiz-Rosas, Ramiro Rafael; Rosas-Martínez, Juana María; Rodríguez-Mirasol, José; Cordero-Alcántara, Tomás[et al.] (MDPI, 2023-05-08)
The aim of this study was to synthesize chemically activated carbons from different agricultural residues, i.e., pistachio shell (PS), bitter orange peel (OP), and saffron petal (SP), and subsequently to use them as supports ... -
Bi-reforming of Biogas for Hydrogen Production with Sulfur-Resistant Multimetallic Catalyst
Poggio-Fraccari, Eduardo; Mariño, Fernando; Herrera, Concepción; Larrubia-Vargas, María Ángeles; Alemany-Arrebola, Luis José (Wiley, 2023)
A multimetallic sample, NiCeSnRh/Al2O3, was tested in methane reforming with a CH4:H2O:CO2 molar ratio equal to 3:2:1. A very stable methane conversion with the time-on-stream was achieved during 20 h. Dimethyl sulfide ... -
Biobased Vanillin Production by Oxidative Depolymerization of Kraft Lignin on a Nitrogen- and Phosphorus-Functionalized Activated Carbon Catalyst
García-Rollán, Miguel; Rivas-Márquez, María Nerea; Bertran-Llorens, Salvador; Deuss, Peter J.; Ruiz-Rosas, Ramiro Rafael; Rosas-Martínez, Juana María; Rodríguez-Mirasol, José; Cordero-Alcántara, Tomás[et al.] (ACS, 2024-04-04)
The sustainable production of vanillin from the oxidative depolymerization of lignin was evaluated. Vanillin was produced from Kraft lignin using heterogeneous catalysts based on activated carbons prepared by chemical ... -
Biomass-derived activated carbon catalysts for the direct dimethyl ether synthesis from syngas
Palomo, José; Rodríguez-Cano, Miguel Ángel; Rodríguez-Mirasol, José; Cordero-Alcántara, Tomás (Elsevier, 2024-02-27)
The direct DME synthesis from syngas was studied by using activated carbon-based bifunctional catalytic beds. Two kinds of activated carbons, prepared by physical (by CO2 partial gasification) and chemical (with phosphoric ... -
Biomass-derived binderless fibrous carbon electrodes for ultrafast energy storage.
Berenguer-Betrián, Raúl; García-Mateos, Francisco José; Ruiz-Rosas, Ramiro Rafael; Cazorla-Amorós, Diego; Morallón, Emilia; Rodríguez-Mirasol, José; Cordero-Alcántara, Tomás[et al.] (Royal Society of Chemistry, 2015-10-14)
The possibility of storing energy efficiently and sustainably at little cost is crucial to prevent climate change and the exhaustion of natural resources. In this work we demonstrate that interconnected and porous carbon ... -
Carbon-based materials as Catalyst Supports for Fischer–Tropsch Synthesis: a review
Valero-Romero, María José; Rodríguez-Cano, Miguel Ángel; Palomo, José; Rodríguez-Mirasol, José; Cordero-Alcántara, Tomás (Frontiers, 2021-02-04)
The use of carbon-based materials as catalyst supports for Fischer–Tropsch synthesis (FTS) is thoroughly reviewed. The main factors to consider when using a carbonaceous catalyst support for FTS are first discussed. Then, ... -
Carbon-supported VPO catalysts with fibrous structure: A new family of catalysts for partial oxidation reactions
Guerrero-Pérez, María Olga; Berenguer-Betrián, Raúl; Ford, Michael; Wachs, Israel E. (Elsevier, 2023-07-15)
The present contribution describes the synthesis of a carbon supported VPO catalyst with a fibrous structure. The synthesis method is simple, low-cost, scalable and reproducible that allows the formation of the bulk mixed ... -
Carbon/H-ZSM-5 composites as supports for bi-functional Fischer-Tropsch synthesis catalysts
Valero-Romero, María José; Sartipi, Sina; Sun, Xiaohui; Rodríguez-Mirasol, José; Cordero-Alcántara, Tomás; Kapteijn, Freek; Gascón, Jorge[et al.] (Royal Society of Chemistry, 2016)
Mesoporous H-ZSM-5–carbon composites, prepared via tetrapropylammonium hydroxide (TPAOH) post treatment of H-ZSM-5 followed by deposition of pyrolytic carbon, have been used as the support for the preparation of Co-based ... -
Chemical reduction of nitrate by zero-valent iron: Shrinking-Core versus Surface Kinetics Models
Villén-Guzmán, María Dolores; Paz-García, Juan Manuel; Arhoun, Brahim; Cerrillo-González, María del Mar; Rodríguez-Maroto, José Miguel; Vereda-Alonso, Carlos; Gómez-Lahoz, César[et al.] (MDPI, 2020-02-12)
Zero valent iron (ZVI) is being used in permeable reactive barriers (PRB) for the removal of oxidant contaminants, from nitrate to chlorinated organics. A sound design of these barriers requires a good understanding of ... -
CO2-SR technology using NiBa unsupported catalyst. Isotopic study of cyclic process of CO2 storage and in situ regeneration with CH4
Molina-Ramírez, Sergio; Peltzer, D.; Cortés-Reyes, Marina; Herrera, C.; Larrubia-Vargas, María Ángeles; Cornaglia, L.; Alemany-Arrebola, Luis José[et al.] (Elsevier, 2023)
The unsupported NiBa catalyst has been used in the CO2-SR (CO2 Storage and in situ Regeneration with CH4) cyclic technology, which allows the use of CO2 from combustion and CH4 from biogas in order to produce enriched ... -
Combined Operando XANES and NMR and ESR Spectroscopies for the Determination of VPO Dynamic States.
Guerrero-Pérez, María Olga; Lapina, Olga B.; Rasmussen, Soren B.; Bañares, Miguel Ángel (Springer, 2023-05-29)
Nanoscaled-VPO (vanadium phosphate oxide) catalysts have been prepared on an alumina support with the objective of obtaining crystallites of the active phase with a high surface-to-volume ratio. Since the catalysed reaction ... -
Comparison of Cu-CHA-zeolites in the hybrid NSR-SCR catalytic system for NOx abatement in mobile sources
Molina-Ramírez, Sergio; Cortés-Reyes, Marina; Herrera-Delgado, María Concepción; Larrubia-Vargas, María Ángeles; Alemany-Arrebola, Luis José (MDPI, 2023-03-10)
DeNOx activity in a NSR–SCR hybrid system of two copper-containing chabazite-type zeolitic catalysts was addressed. A Pt-Ba-K/Al2O3 model catalyst was used as the NSR (NOx storage and reduction) catalyst. For the SCR ...