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dc.contributor.authorPalacios Corella, Mario
dc.contributor.authorFernández Espejo, Alejandro
dc.contributor.authorBazaga-García, Montse
dc.contributor.authorRamírez-Losilla, Enrique 
dc.contributor.authorCabeza-Díaz, Aurelio 
dc.contributor.authorClemente-León, Miguel
dc.contributor.authorCoronado, Eugenio
dc.date.accessioned2021-02-25T09:40:49Z
dc.date.available2021-02-25T09:40:49Z
dc.date.created2020-02-24
dc.date.issued2017-11-01
dc.identifier.citationInorg. Chem. 2017, 56, 22, 13865–13877es_ES
dc.identifier.urihttps://hdl.handle.net/10630/20985
dc.description.abstractThe syntheses, structures, magnetic, and proton conductivity properties of a family of bimetallic anilate-based compounds with inserted alkylammonium cations are presented. The structures of (Me2NH2)[MnIICrIII(Br2An)3]·2H2O (1), (Et2NH2)[MnIICrIII(Br2An)3] (2), (Et3NH)[MnIICrIII(Cl2An)3] (3), and [(Et)(i-Pr)2NH]-[MnIICrIII(Br2An)3]·(CHCl3)0.5·(H2O) (4) contain a 2D anionic network formed by Mn(II) and Cr(III) ions linked through anilate ligands. In 1, 2, and 3, the hexagonal holes of this network are occupied by Me2NH2+, Et2NH2+, or Et3NH+ cations. Interestingly, the small increase of size of the templating cation in 4 ([(Et)(i-Pr)2NH]+ in the place of Me2NH2+, Et2NH2+ or Et3NH+), gives rise to a different structure with half of the cations placed within the layers and the other one in the space between the layers. This leads to bilayers with an interlayer separation similar to those of 1, 2, and 3 separated by larger interbilayer distances. Compounds 1, 2, and 3 show a ferrimagnetic ordering with a Tc of 8.0 K (1), 8.9 K (2), and 8.0 K (3). In 4, the presence of different interlayer distances leads to a metamagnetic behavior when the sample is measured in contact with the mother liquor. The behavior changes in the dry sample, which shows a ferrimagnetic ordering as that of 1, 2, and 3 due to collapse of the structure as confirmed by powder X-ray diffraction. Interestingly, the metamagnetic behavior is recovered after reimmersing the crystals in the mother liquor proving the reversibility of the process. All solids are Grotthuss-type proton conductors with conductivity values ranging between 2.3 × 10−6 S·cm−1 for 3 and 2.4 × 10−5 S·cm−1 for 1 measured at 70 °C and 95% relative humidity and activation energies of ∼0.2 eV.es_ES
dc.description.sponsorshipEU (ERC Advanced Grant SPINMOL) CTQ2014-52758-P, MAT-2014-56143-R y MAT2016-77648-R del MINECO Unidad de Excelencia María de Maeztu MDM-2015-0538 de la Generalitat Valenciana P12-FQM-1656 de la Junta de Andalucíaes_ES
dc.language.isoenges_ES
dc.publisherACS publicationses_ES
dc.rightsinfo:eu-repo/semantics/openAccesses_ES
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/*
dc.subjectImanes superconductoreses_ES
dc.subjectEspectroscopíaes_ES
dc.subjectAnioneses_ES
dc.subject.otherAnilate-Based Magnetses_ES
dc.subject.other2,5-Dihydroxy-1,4-benzoquinone Dianion Derivativeses_ES
dc.subject.otherProton-conductivityes_ES
dc.titleInfluence of Proton Conducting Cations on the Structure and Properties of 2D Anilate-Based Magnetses_ES
dc.typeinfo:eu-repo/semantics/articlees_ES
dc.centroFacultad de Cienciases_ES
dc.identifier.doi10.1021/acs.inorgchem.7b01965
dc.rights.ccAttribution-NonCommercial-NoDerivatives 4.0 Internacional*
dc.type.hasVersioninfo:eu-repo/semantics/publishedVersiones_ES


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