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dc.contributor.authorTorres-Liñán, Javier 
dc.contributor.authorRodríguez-Mirasol, José 
dc.contributor.authorCordero-Alcántara, Tomás 
dc.contributor.authorRosas-Martínez, Juana María 
dc.date.accessioned2019-12-13T11:26:09Z
dc.date.available2019-12-13T11:26:09Z
dc.date.created2019
dc.date.issued2019
dc.identifier.citationAbstract book of 8th International Conference on Carbon for Energy Storage and Environmental Protection (2019) 160. Alicante (Spain)en_US
dc.identifier.urihttps://hdl.handle.net/10630/19043
dc.description.abstractThe aim of this work is the study of the deactivation and regeneration of a Zr-loading P-containing carbon catalyst on the dehydration of methanol to dimethyl ether. The Zr carbon-based catalyst showed a good performance in the methanol to DME reaction, with a high activity and selectivity to dimethyl ether (DME) at temperatures between 400-600ºC. Coke deposition reduces the activity and selectivity TO DME. Methane formation also increases with coke formation. Coke production takes place mainly on the narrow micropores at higher temperatures, firstly on Zr and then on P surface sites. Porosity parameters values remain the same after catalyst regeneration by oxidation treatment. Only a small fraction of coke is burnt due to the air treatment. The zirconium hydrogenphosphate specie seems to be the responsible of the long-term activity of the catalyst.en_US
dc.description.sponsorshipUniversidad de Málaga. Campus de Excelencia Internacional Andalucía Tech.en_US
dc.language.isoengen_US
dc.publisherUniversidad de Alicanteen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectQuímicaen_US
dc.subject.otherDimathyl Etheren_US
dc.subject.otherCarbon-based catalysten_US
dc.subject.otherZren_US
dc.subject.otherMethanolen_US
dc.titleCatalyst deactivation and regeneration for MTD reaction on Zr carbon-based catalysten_US
dc.typeinfo:eu-repo/semantics/conferenceObjecten_US
dc.relation.eventtitle8th International Conference on Carbon for Energy Storage and Envieronmental Protectionen_US
dc.relation.eventplaceAlicanteen_US
dc.relation.eventdate20-24 de octubre de 2019en_US


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