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Listar por autor "Hartl, František"
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Caracterización de sistemas basados en carbazol con transformación reversible entre birradical aislado y σ-agregados
Badía-Domínguez, María Irene; Gámez-Valenzuela, Sergio; Capel-Ferrón, Cristina; Ponce-Ortiz, Rocío; López-Navarrete, Juan Teodomiro; Hernández-Jolín, Víctor; Hartl, Frantisek; Li, Hongxiang; Ruiz-Delgado, María del Carmen[et al.] (2017-07-03)El desarrollo de la química de moléculas orgánicas π-conjugadas que tienen una capa de valencia que no está completamente llena, también conocidas como sistemas de capa abierta, ha atraído mucho interés en estos últimos ... -
Carbazole and indolcarbazole-based systems: impact of the structural changes on the system properties
Badía-Domínguez, María Irene; Hartl, Frantisek; Li, Hongxiang; Seki, Shu; Sakamaki, Daisuke; Negri, Fabrizia; López Navarrete, Juan T.; Hernández-Jolín, Víctor; Ruiz-Delgado, María del Carmen[et al.] (2022)π-Conjugated diradical compounds, featuring unique unsaturated valences and radical centres in the ground state, are fundamentally important for understanding the nature of chemical bonds and have potential applications ... -
Carbazole-based Diradicals for Dynamic Covalent Chemistry
Ruiz-Delgado, María del Carmen; Hartl, Frantisek; Li, Hongxiang; Sancho-García, Juan C.; Pérez Guardiola, Andrés; Rodríguez-González, Sandra; López-Navarrete, Juan Teodomiro; Hernández-Jolín, Víctor; Badía-Domínguez, María Irene[et al.] (2020-01-29)Dynamic covalent chemistry (DCC) is focused on the creation of structural scaffolds based on chemical components that interact through strong but reversible bonds. In fact, dynamic covalent bonds receive lot of attention ... -
Cyclophane self-assembly from carbazole-based diradicals
Badía-Domínguez, María Irene; Hartl, Frantisek; Hongxiang, Li; Seki, Shu; López-Navarrete, Juan Teodomiro; Hernández-Jolín, Víctor; Ruiz-Delgado, María del Carmen[et al.] (2022-06-30)The investigation of π-conjugated diradical compounds, featuring radical centers in the ground state, is key to understanding the nature of chemical bonds.[1] Occasionally, these systems can form long σ C-C bonds between ... -
Dicyanomethylene-substituted indolocarbazole diradicals: Investigating their challenging chemical reactivity and physical properties.
Badía-Domínguez, María Irene; Wang, Deliang; Nash, Rosie; Hernández-Jolín, Víctor; Li, Hongxiang; Hartl, František; Ruiz-Delgado, María del Carmen[et al.] (2024)π-Conjugated diradical compounds, with unpaired electrons in the ground state, are fundamentally important for understanding the nature of chemical bonds and have potential applications in material science[1]. It has been ... -
Dynamic Covalent Properties of a Novel Indolo[3,2-b]carbazole Diradical
Badía-Domínguez, Irene; Peña-Álvarez, Miriam; Wang, Deliang; Pérez Guardiola, Andrés; Vida-Pol, Yolanda; Rodríguez-González, Sandra; López Navarrete, Juan T.; Hernández-Jolín, Víctor; Sancho-García, Juan C.; García-Baonza, Valentín; Nash, Rosie; Hartl, František; Li, Hongxiang; Ruiz-Delgado, María del Carmen[et al.] (Wiley, 2021)This work describes the synthesis and properties of a dicyanomethylene-substituted indolo[3,2-b]carbazole diradical ICz-CN. This quinoidal system dimerises almost completely to (ICz-CN)2, which contains two long C(sp3)−C(sp3) ... -
Estudio del efecto fotocrómico reversible de un sistema quinoide basado en carbazol
Gámez-Valenzuela, Sergio; Badía-Domínguez, María Irene; Capel-Ferrón, Cristina; Ponce-Ortiz, Rocío; López-Navarrete, Juan Teodomiro; Hernández-Jolín, Víctor; Hartl, Frantisek; Li, Hongxiang; Ruiz-Delgado, María del Carmen[et al.] (2017-07-03)Hoy en día, el uso de materiales de naturaleza orgánica se presenta como un recurso ecológico y asequible para el diseño de dispositivos electrónicos. Entre ellos, los materiales sensibles a estímulos tienen además numerosas ... -
Formation of stimuli-responsive cyclophanes by self-assembly: the case of carbazole-based biradicals
Ruiz-Delgado, María del Carmen; Badía-Domínguez, María Irene; Hernández-Jolín, Víctor; Hartl, Frantisek; Hongxiang, Li; Sancho-García, Juan C.; Pérez Guardiola, Andrés; Rodríguez-González, Sandra[et al.] (2019-01-16)Dynamic covalent bonds has recently received lot of attention because of their unique feature to become reversible under mild conditions.[1] In this context, π-conjugated biradical compounds has emerged as essential building ... -
Impact of the dicyanomethylene substitution position on the cyclophane macrocycle formation in carbazole-based biradicals
Badía-Domínguez, María Irene; Sakamaki, Daisuke; Seki, Shu; Hartl, Frantisek; López-Navarrete, Juan Teodomiro; Hernández-Jolín, Víctor; Ruiz-Delgado, María del Carmen; Hongxiang, Li[et al.] (2019-01-16)π-Conjugated biradical compounds, featuring unique unsaturated valences and radical centers in the ground state, are fundamentally important for understanding the nature of chemical bonds and have potential applications ... -
Multiresponsive chromic soft materials: formation of strongly coupled σ-dimers from IndoloCarbazole-based biradicaloids
Hartl, Frantisek; Li, Hongxiang; Badía-Domínguez, María Irene; Sancho-García, Juan C.; Pérez Guardiola, Andrés; Rodríguez-González, Sandra; López-Navarrete, Juan Teodomiro; Hernández-Jolín, Víctor; Ruiz-Delgado, María del Carmen[et al.] (2018-12-18)Dynamic covalent chemistry is focused on the creation of structural scaffolds based on chemical components that interact through strong but reversible bonds. In fact, dynamic covalent bonds receive lot of attention because ... -
Pi-Dimerization of Oligothienoacene Radical Cations
Ruiz-Delgado, María del Carmen; Capel-Ferrón, Cristina; Capdevila-Cortada, Marçal; Hartl, Frantisek; Hernández-Jolín, Víctor; Novoa, Juan J.; López-Navarrete, Juan Teodomiro[et al.] (2014-10-29)Oligothienoacenes, the fused-ring analog of -linked oligothiophenes, belong to the most promising candidates for organic electronic applications. This is in part due to their densely packed solid-state structures resulting ... -
pi-Dimerization of Oligothienoacene Radical Cations
Ruiz-Delgado, María del Carmen; Capel-Ferrón, Cristina; Capdevila-Cortada, Marçal; Novoa, Juan j; Hartl, Frantisek; Hernández-Jolín, Víctor; López-Navarrete, Juan Teodomiro[et al.] (2015-06-23)Oligothienoacenes, the fused-ring analog of α-linked oligothiophenes, belong to the most promising candidates for organic electronic applications. This is in part due to their fully planar structure that avoids conformational ... -
π-Dimerization of Heptathienoacene Radical Cations
Ruiz-Delgado, María del Carmen; Capel-Ferrón, Cristina; Capdevila-Cortada, Marçal; Hartl, Frantisek; Hernández-Jolín, Víctor; Novoa, Juan J.; López-Navarrete, Juan Teodomiro[et al.] (2014-02-24)Oligothienoacenes, the fused-ring analog of pi-linked oligothiophenes, belong to the most promising candidates for organic electronic applications. This is in part due to their fully planar structure that avoids conformational ...