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Ammonia effects on proton conductivity properties of coordination polymers
Pérez-Colodrero, Rosario Mercedes; Salcedo, Inés R.; Bazaga-García, Montse; Olivera-Pastor, Pascual; Moreno-Real, Laureano; Losilla, Enrique R.; Cabeza-Díaz, Aurelio[et al.] (2016-09-22)Crystalline metal phosphonates are referred to as a type of structurally versatile coordination polymers [1]. Many of them contain guest molecules (H2O, heterocyclics, etc.), acidic sites and, furthermore, their structure ... -
Proton conductivity of multifunctional metal phosphonate frameworks
Cabeza-Díaz, Aurelio; Bazaga-García, Montse; Pérez-Colodrero, Rosario Mercedes; Papadaki, M.; Olivera-Pastor, Pascual; Losilla, Enrique R.; León-Reina, Laura; Moreno-Real, Laureano; García-Aranda, Miguel Ángel; Demadis, Konstantinos D.[et al.] (2015-03-23)Metal phosphonates exhibit attractive characteristics for proton conductivity, such as tunable functionality, chemical and thermal stability and the existence of H-bond networks with acidic protons within their structure.1 In ... -
Structural variability in M2+ 2-hydroxyphosphonoacetate moderate proton conductors
Pérez-Colodrero, Rosario Mercedes; Salcedo, Inés R.; Bazaga-García, Montse; Milla-Pérez, Diego F.; Durán-Martín, Jonatan D.; Ramírez-Losilla, Enrique; Moreno-Real, Laureano; Rius, Jordi; García-Aranda, Miguel Ángel; Demadis, Konstantinos D.; Olivera-Pastor, Pascual; Cabeza-Díaz, Aurelio[et al.] (De Gruyter, 2017)The structural variability of two series of Mg2+- and Zn2+- 2-hydroxyphosphonoacetates have been studied in the range of 25–80 °C and 95 % relative humidity in order to correlate the structure with the proton conductivity ...